Dear friends, colleagues, and all HPx-eos/THERMOCALC users,
There will be a hiatus in news, as, in common with the rest of the global community, we work to handle the effects of the COVID-19 pandemic on our professional and personal lives. I hope to return to website developments in June, after the end of semester.
Wishing all of you the very best at this difficult time,
Corinne Frigo has been visiting Melbourne from ANU. Corinne is working with Hugh O’Neill, Richard Arculus and Eleanor on ARC Discovery Project DP170100982, A new perspective on melting in the Earth and the origin of basalts. She has some very interesting experimental results on peridotite melting in CMAS + Cr2O3 + K2O at 30 kbar, which contrast nicely with the experiments of Liu & O’Neill (2004) at 11 kbar.
The experiments are giving the x-eos a workout! Currently, the model pyroxenes are taking too much Al2O3 in high-Cr2O3 bulk compositions, meaning that we should revise the Al-Cr partitioning here. Experiments in small systems are extremely useful, providing constraints that can’t be extracted from the natural system data available. Eleanor and Corinne will continue to look at this problem over the next few months, and their new insights will ultimately be incorporated into the next generation of igneous x-eos.
New to phase diagram modelling? Always wanted to know how petrogenetic grids were made but didn’t dare to ask? Worry no more! Here’s the first of a series of tutorials, a simple, step-by-step guide to build your own P-T projection with THERMOCALC!
Looking ahead, Eleanor and John have just been discussing TawnyCALC, one of two upcoming extension packs to THERMOCALC.
TawnyCALC will automate various problems that involve driving THERMOCALC along a path, doing dogmin calculations at each step. Fractionation calculations are an obvious example. We currently plan to have it running online via a Jupyter interface.
The second extension pack, TammaCALC, will allow a set of phase diagram calculations to be made simultaneously and repeatedly. It will facilitate various uncertainty calculations.
This is Simon’s blog reporting on the development of a new single-clinopyroxene HPx-EOS.
The new model is designed to replace pre-existing versions that do not currently overlap in P—T—x space.
So far three clinopyroxene EOS exist. Ordered diopside—omphacite—jadeite (Green et al., 2007) is for coexisting sodic—calcic clinopyroxenes. It accounts for order—disorder on the octahedral M1 and M2 sites, but not on the tetrahedral T sites. It is appropriate for high pressure but unsuitable for high temperatures.
We’re delighted to welcome John Mansour onto the development team. John is a programmer who has worked extensively on the Underworld geodynamics code. He will be helping us with (i) facilitating open-system calculations in THERMOCALC, and (ii) working towards the integration of phase equilibrium calculations with Underworld.
Eleanor has been at the Australian National University in Canberra visiting Corinne Frigo. Corinne has recently begun a complex program of experiments on the generation of basalt-analogue melts in the CMAS±Cr system. The new igneous set of HPx-eos do not agree too well with Corinne’s initial experiments. This is not really a surprise at this stage, but we have some work to do before we can understand what is wrong.
Corinne is working with Hugh O’Neill, Richard Arculus and Eleanor on ARC Discovery Project DP170100982, A new perspective on melting in the Earth and the origin of basalts. In this project we have the opportunity for close interaction between the experimental program and the internally-consistent modelling work. Enlightening and fun! Corinne will present some of this work at Goldschmidt on 21st August.